Product ID:A/W HYDRAULIC OIL 46, 33-420
MSDS Date:10/07/1997
FSC:9150
NIIN:00N069410
Status Code:A
MSDS Number: CHTCK

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 918-495-4700;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

REFINED PETROLEUM OILS (CONTAINING INGS 2-7).

RTECS: 9999999ZZ

Fraction By Weight: 98-100%

OSHA PEL 5MG/M3 OIL MIST(MFR)

ACGIH TLV: 5MG/M3 OIL MIST(MFR)

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT REFINED

CAS: 64741-88-4

RTECS: PY8040501

OSHA PEL 5MG/M3 OIL MIST(MFR)

ACGIH TLV: 5MG/M3 OIL MIST(MFR)

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED

CAS: 64741-89-5

RTECS: PY8041501

OSHA PEL 5MG/M3 OIL MIST(MFR)

ACGIH TLV: 5MG/M3 OIL MIST(MFR)

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY

CAS: 64742-65-0

RTECS: PY8038501

OSHA PEL 5MG/M3 OIL MIST(MFR)

ACGIH TLV: 5MG/M3 OIL MIST(MFR)

SOLVENT REFINED, HYDROTREATED LIGHT PARAFFINIC DISTILLATE

CAS: 64742-55-8

RTECS: PY8036500

OSHA PEL 5MG/M3 OIL MIST(MFR)

ACGIH TLV: 5MG/M3 OIL MIST(MFR)

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)

CAS: 64742-54-7

RTECS: PY8035501

OSHA PEL 5MG/M3 OIL MIST(MFR)

ACGIH TLV: 5MG/M3 OIL MIST(MFR)

HIGHLY REFINED BASE OIL

CAS: 72623-87-1

OSHA PEL 5MG/M3 OIL MIST(MFR)

ACGIH TLV: 5MG/M3 OIL MIST(MFR)

ANTI-OXIDANT/ANTI-WEAR AGENT (MAY CONTAIN ING 9).

Fraction By Weight: 0-2%

OSHA PEL N/K

ACGIH TLV: N/K

ZINC DIALKYLDITHIOPHOSPHATE

RTECS: TD5550000

OSHA PEL N/K

ACGIH TLV: N/K

(ORAL,RAT) >5 G/KG.

Fraction By Weight: <1%

OSHA PEL N/K

ACGIH TLV: N/K

INJECTION UNDER SKIN,

RTECS: 9999999ZZ

VISCOSITY RANGE OF PRODS

RTECS: 9999999ZZ

UPON INGEST, THERE IS SLIGHT RISK OF ASPIR INTO

RTECS: 9999999ZZ

EMESIS MAY BE CONSIDERED FOR EVACUATION OF MATERIAL.

RTECS: 9999999ZZ

PROMPT SURGICAL DEBRIDEMENT.

RTECS: 9999999ZZ

EVACUATE AREA IN EVENT OF SIGNIFICANT SPILLS.

RTECS: 9999999ZZ

PROT. USE PROT CLTHG. CONTAIN SPILL IN TEMPORARY

RTECS: 9999999ZZ

DO NOT ALLOW MATL TO ESCAPE INTO SEWERS, GROUND

RTECS: 9999999ZZ

AID. REPORT RELS AS REQD TO APPROP FED, STATE & LOC

RTECS: 9999999ZZ

OIL INJECTED INTO SKIN FROM HIGH PRESS

RTECS: 9999999ZZ

OCCURS DURING FIRST FEW HRS. SEEK MED ATTN IMMED.

RTECS: 9999999ZZ

FROM RPTD/PRLNG EXPOS. DO NOT STORE MATL IN

RTECS: 9999999ZZ

REFER TO SPECIAL PROT INFO SECTION.

RTECS: 9999999ZZ

USE PPE IF DIRECT CONT IS ANTIC. ELIM HEAT & IGNIT

RTECS: 9999999ZZ

FROM HIGH PRESS LEAKS IN HYDRAULIC SYS. KEEP UNNEC

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:IN ENCLSD SPACES/WHEN HOT,
VAPS MAY REACH CONCS SUFFICIENT TO CAUSE DROW, DIZZ, HDCH,
NAUS/LUNG IRRIT. ELEVATED MIST CONCS WELL ABOVE APPLIC WORKPLACE
EXPOS LEVELS MAY CAUSE SEV LUNG DMG. SKIN/EYE:THIS MATL MAY CAUSE
MILD TRANSIENT IRRIT. INGEST:THIS MATL MAY ENTER LUNGS BY ASPIR &
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SEV DMG. UPON INGEST, GI DISCOMFORT,
DIARR & HDCH MAY OCCUR. INJECTION:INJECTION UNDER SKIN, IN
MUSCLE/INTO BLOOD STREAM MAY CAUSE IRRIT, INFLAMM, SWELL/SEV, PERM
TISS DMG. MOST DMG OCCURS DU RING FIRST FEW HRS. CHRONIC:PRLNG &/OR
FREQUENT CONT MAY CAUSE DRYING, CRACKING (DERM)/FOLLICULITIS.
Medical Cond Aggravated by Exposure:NONE.

First Aid:INHAL:MOVE VICTIM TO FRESH AIR. IF VICTIM IS NOT BRTHG, IMMED
BEGIN CPR. IF BRTHG IS DFCLT, 100% HUMIDIFIED OXYG SHOULD BE GIVEN
BY QUALIFIED INDIVIDUAL. SEEK MED ATTN IMMED. SKIN:WASH EXPOS SKIN
W/SO AP & WATER. REMOVE CONTAM CLTHG. LAUNDER BEFORE USE. SEEK MED
ATTN IF TISS APPEARS DMGD/IF IRRIT PERSISTS. EYES:FLUSH W/LG VOLS
OF WATER. SEEK MED ATTN IF PAIN, EXCESSIVE TEARING/IRRIT (SUPP
DATA)

Flash Point Method:OC
Flash Point:>365F,>185C
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING. MATERIAL MAY BE
IGNITED BY SPARKS OR FLAMES.

Spill Release Procedures:REMOVE ALL IGNIT SOURCES. ISOLATE AREA OF
SPILL & RESTRICT ACCESS TO PERS WEARING PROT CLTHG. VENT AREA OF
RELS, AS NEC, TO DISPERSE VAPS & MISTS. SM SPILLS:ABSORB RELS MATL
W/NON-COMBUST ABSORB. PLAC E INTO CNTNRS FOR LATER DISP. LG SPILLS:
(ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. DO NOT APPLY HEAT OR FLAME TO CONTAINER. KEEP SEPARATE FROM
STRONG OXIDIZING AGENTS.
Other Precautions:EMPTY CNTNRS MAY CONTAIN COMBUST PROD RESIDUES WHICH
COULD IGNITE W/EXPLO FORCE. CONSULT APPROP FED, STATE & LOC AUTHS
BEFORE REUSING, RECONDITIONING, RECLAIMING, RECYCLING/DISP OF EMPTY
CNTNRS &/OR W ASTE RESIDUES OF THIS PROD. (ING 20)

Respiratory Protection:AT ELEVATED TEMPERATURES OR IN ENCLOSED AREAS,
VAPOR OR MIST CONCENTRATIONS MAY EXCEED APPLICABLE WORKPLACE
EXPOSURE LEVELS. USE NIOSH APPROVED ORGANIC VAPOR OR MIST CHEMICAL
CARTRIDGE RESPIRATOR WHEN ELEVATED AIRBORNE CONCS ARE ANTIC.
Ventilation:USE IN WELL VENTED AREA. IN CONFINED SPACES, MECH VENT MAY
BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (SUPDAT)
Protective Gloves:IMPERVIOUS GLOVES(HEAVY NITRILE RUBBER).
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR BODY-COVERING WORK CLOTHES TO AVOID PRLNG/RPTD
EXPOSURE.
Work Hygienic Practices:WASH EXPOSED SKIN THOROUGHLY W/SOAP & WATER.
REMOVE CONTAMINATED CLOTHING. LAUNDER BEFORE REUSE.
Supplemental Safety and Health
SPEC GRAV:0.86-0.89 (H*2O=1). VP:1X10-5 TO 2X10-4 @ 25C. WASTE DISP
METH:YOUR REGIONAL U.S. EPA OFFICE FOR GUIDANCE CONCERNING CASE
SPECIFIC DISP ISSUES. VENT:APPLIC WORKPLACE EXPOS LEVELS AS
EVALUATE D BY DESIGNATED & PROPERLY TRAINED PERS. FIRST AID
PROC:PERSISTS. INGEST:INDUCE VOMIT ONLY UPON ADVICE OF MD. (ING 11)

Boiling Pt:B.P. Text:>560F,>293C
Vapor Pres:SUPP DATA
Vapor Density:>1
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER LIQUID; MILD PETROLEUM ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
THIS PRODUCT MAY REACT W/STRONG OXIDIZERS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CO*2, CO W/INCOMPLETE COMBUSTION &
POTENTIAL TRACE OXIDES OF PHOSPHOROUS, SULFUR & ZINC.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . IT IF
THE RESPONSIBILITY OF USER TO DETERM IF MATL IS HAZ WASTE AT TIME
OF DISP. DETERM COMPLIANCE STATUS W/ALL APPLIC REQUIREMENTS PRIOR
TO DISP. CONT RCRA/SUPERFUND HOTLINE AT (800)424-9346/ (SUPDAT)

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.